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Q.

1g sample of H2O2 solution containing x% H2O2 by weight requires x mL of K2Cr2O7 solution for
complete oxidation under acidic conditions. The molarity of K2Cr2O7 solution is —— .

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answer is 0.5.

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Detailed Solution

3H2O2 + K2Cr2O2 + 4H2SO4 K2SO4 + Cr2(SO4)3 + 7H2O + 3O2 
M eq of H2O2 = m eq of K2Cr2O7

100g of H2O2 solution contains x gof H2O2= Weightof H2O2m Eq of H2O2= Weightof H2O2×103EEwHH2O2=5.1x100×117×103=3xmEqCr2O72H2O2mEqmEqN1V1(mL)3xN1×xmL=3xNK2Cr2O7=3NMK2Cr2O7=Nn=0.5M 

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