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Q.

2 mole of AB(s) is taken in close container of volume of 2 litre. If 1 mole of  AB(s) has taken part in reaction to attain the equilibrium state and equilibrium moles of D2(g)   is 0.75.
 AB(s)A(g)+B(g)                      KC=a(mol/l)2 A(g)12C2(g)+32D2(g)                     KC=b(mol/l2)
 
at equilibrium  [A]=x(mol/litre)[C2]=y(mol/litre)
Calculate the value of b3a(x+y)   is ……
 

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answer is 12.

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Detailed Solution

AB(s)21A(g)1x1+B1(g)      A(g)1x112C2(g)x12+32D2(g)3x12    3x12=0.75   x1=12 a=12×14=18(mole/litre)2    b=(38)3/2(18)1/2(14)=3316 x=[A]=14M    y=[C2]=18M    b3a(x+y)=33×31618(14+18)=91618×38=916×643=12

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