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Q.

2 mole of ideal gas expands isothermally and reversibly from 1 L to 10 L at 300 K, Then ΔH is:

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a

4.98kJ

b

11.47kJ

c

zero

answer is C.

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Detailed Solution

n = 2 moles
T = 300 K

Vf=10LV1=1L

R = Gas constant =8.314J/Kmol

Substituting these values in eqn(1), we have

W=2.303×2×8.314×300×log101W=11488.285J=11.4kJ

Now as we know that,

ΔH=ΔU+W

For an isothermal process,

ΔU=0ΔH=W=11.4kJ

Hence the enthalpy for the given process is 11.47kJ.

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2 mole of ideal gas expands isothermally and reversibly from 1 L to 10 L at 300 K, Then ΔH is: