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Q.

20 mL of H2O2 is reacted completely with acidified K2Cr2O7 solution. 40 mL of K2Cr2O7 solution is required to oxidise the H2O2 completely. Also, 2.0 mL of the same K2Cr2O7 solution is required to oxidise 5.0 mL of a 1.0 M H2C2O4 solution to reach equivalence point. Which of the following statements is/are correct?

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a

The volume strength of H2O2 is 112V.

b

If 40 mL more 5M/8H2O2 is further added to the 10 mL more H2O2 solution, the volume strength of the resulting solution is changed to 16.8 V.

c

The volume strength of H2O2 is 56V.

d

The H2O2 solution is 5M.

answer is A, B, D.

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Detailed Solution

i.  mEq of H2O2=mEq of Cr2O72(n=2)                                          (n=2)   (x)

20mL×N1=40mL×N2

a. mEq of Cr2O72mEq of C2O42   . . . . . (i)

                                             (n=2)

2.0×N25.0×1.0×2

N2Cr2O72=5                             . . . .(ii)

Substituting the value of N2 from (ii) in (i)

20mL×N1=40mL×5M1H2O2=102=5M

 b. 1NH2O2=5.6V

10NH2O2=56V

 d. N1V1+N2V2=N3V3V3=10+40=50mL

10×10+40×58×2=N3×50N3H2O2=3N

The volume strength of H2O2=5.6×3=16.8V

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