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20 ml of $\frac{M}{10} C H_{3} C O O H$ solution is titrated with $\frac{M}{10}$ solution of NaOH. When 16 ml of NaOH solution is added to the $C H_{3} C O O H$ solution a buffer solution was formed and when 20 ml of NaOH solution was added complete neutralization took place $p K_{a}$ of $C H_{3} C O O H$ is 4.74. ( $\log 2 = 0.3, \log 5 = 0.7$ )

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