Q.

2.2 moles of phosphorus penta chloride were taken in a closed vessel and dissociated into phoshorus trichloride and chlorine. At equilibrium, the total number of moles of the reactants and the products was 2.53. The degree of dissociation is;

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a

0.15

b

0.165

c

0.30

d

0.33

answer is C.

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Detailed Solution

It is given to find the degree of dissociation.2.2 moles of phosphorus penta chloride were taken in a closed vessel and dissociated into phoshorus trichloride and chlorine. At equilibrium, the total number of moles of the reactants and the products was 2.53.

PCl5PCl3+Cl2

Initially Mole 2.2

After dissociate 2.2(1-α)  2.2  2.2

Total moles =2.2-2.2c+2.2+2.2c

=2.2(1+c)=2.53

Alpha=0.15 Ant 

Hence the correct option is (C) 0.15

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