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Q.

25.5 g of H2O2 solution on decomposition gave 1.68L of O2 at STP. The percentage strength by weight of the solution is

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a

10

b

25

c

20

d

30

answer is C.

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Detailed Solution

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Balanced equation for decomposition of H2O2

2H2O22H2O+O2

2mole H2​O2​ will produce 1 mol O2​ 

At STP 1 mole O2​ has volume = 22.4L
?????------------------------------------ At STP 1.68L of O2​  

1.68×122.4=0.075 mole of  O2​ 

Moles of hydrogen peroxide is twice the moles of oxygen gas, therefore the mole of hydrogen peroxide is 0.15 moles (0.075 mol×2).

mass of H2O2 = 34 gms

Mass of H2O2 decomposed  

moles = massmolar mass

0.15 =mass34 mass=5.1gms

5.1 gms of H2O2 in 25.5 gms solution

100 gms of H2O2-------???    

=20%

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