Banner 0
Banner 1
Banner 2
Banner 3
Banner 4
Banner 5
Banner 6
Banner 7
Banner 8
Banner 9

Q.

2.5 ml of (2/5) M weak monoacidic base (Kb=1×1012at 25°) (2/15) M HCl in water at 25°C. The concentration of H+ at equivalence point is (Kw=1×1014 at 25C)

see full answer

Your Exam Success, Personally Taken Care Of

1:1 expert mentors customize learning to your strength and weaknesses – so you score higher in school , IIT JEE and NEET entrance exams.
An Intiative by Sri Chaitanya

a

2.7×102M

b

3.7×1014M

c

3.2×102M

d

3.2×107M

answer is D.

(Unlock A.I Detailed Solution for FREE)

Best Courses for You

JEE

JEE

NEET

NEET

Foundation JEE

Foundation JEE

Foundation NEET

Foundation NEET

CBSE

CBSE

Detailed Solution

Let the weak monoacidic base be BOH, then the reaction that occurs during titration is 

BOH+HClBCl+H2O  Equilibrium: B+c(1h)+H2OBOHch+H+
Using the normality equation, N1V1= (acid) N2V2 (base) 
Substituting various given values, we get 
215V1=2.5×215  or V1=2.5×25×152=2.5×3=7.5ml

Then the concentration of BCl in resulting solution is given by 
[BCl]=25×2.510=110 or 0.1M [ Total volume =2.5+7.5=10ml]  Since Kh=KwKb Kh=1×10141×1012=102  Thus Kh=0.1h2(1h) or 102=0.1h2(1h)  or 102102h=0.1h2  or 0.1h2+102h102=0
(Solving this quadratic equation for h, we get) 
 Using x=b±b24ac2a h=102±1022+4×101×1022×0.1 =102±104+4110320.1 =0.01±.0001+0.0040.2 =0.01±0.00410.2 =0.01±0.0640.2 =0.540.2 =0.27 H+=c.h=0.1×0.27=2.7×102M Thus the correct answer is [d].  

Watch 3-min video & get full concept clarity
score_test_img

courses

No courses found

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Get Expert Academic Guidance – Connect with a Counselor Today!

best study material, now at your finger tips!

  • promsvg

    live classes

  • promsvg

    progress tracking

  • promsvg

    24x7 mentored guidance

  • promsvg

    study plan analysis

download the app

gplay
mentor

Download the App

gplay
whats app icon
personalised 1:1 online tutoring