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Q.

25 ml of a solution of barium hydroxide on titration with a 0.1 molar solution of hydro chloric acid gave a titre value of 35 ml. The molarity of barium hydroxide solution was

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a

0.07

b

0.14

c

0.28

d

0.35

answer is A.

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Detailed Solution

Ba(OH)2+2HClBaCl2+H2O

Ba(OH)2                               HCl

M1=?                  M2=0.1M

V1=25 mL              V2=35mL

n1=1              n2=2

M1V1n1=M2V2n2

M1=M2V2n2×n1V2

=0.1×352×125=7100=0.07

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