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Q.

25 mL of silver nitrate solution (1M) is added dropwise to 25 mL of potassium iodide (1.05 M) solution. The ion(s) present in very small quantity in the solution is/are

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a

Ag+ and I both 

b

I only

c

NO3 only 

d

K+ only 

answer is A.

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Detailed Solution

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            AgNO3(aq)25mmol  +  KI(aq)25×1.05mmol  AgI(s)0       +  KNO3(aq)0 Finally   0                1.25 m mol       25 m mol     25 m mol AgI(s) Ag(aq)++I(aq) (only slightly dissociated) Ag+&Iare present in very small quantity as AgI precipitates  and feebly dissociates due to its low Ksp value 

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