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Q.

250 mL of 1M, I2 molar is separately reacted with 0.5 M Cu2S solution, 0.5 M CuS solution and 0.5 M S2O32- solution, causing production of Cu+2 and SO42- in the first two and S4O62- in the last case along with iodide ions. Which of the following options is /are correct assuming 100% completion of the reaction?

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a

125 ml of CuS solution will be consumed.
 

b

500 ml of S4O62- solution will be consumed.

c

Equivalent weight of l2 in each of the reactions will be 127.

d

100 ml of CuS solution will be consumed.

answer is A, B, D.

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Detailed Solution

Cu2S (nf=10)  +     I2(nf=2)        Cu+2   +    SO4-2     +    I-       .....(1) CuS (nf=8)  +     I2(nf=2)        Cu+2   +    SO4-2     +    I-       .....(2) I2 (nf=2)  +     S2O3-2(nf=1)          I-   +    S4O6-2     (nf=2)      .....(3) 

In reaction (1):

Meq of Cu2S = Meq of I2  0.5 × 10 × V = 250 × 1 × 2  V = 100 ml (of Cu2S)

In reaction (2):

Meq of CuS = Meq of I2  0.5 × 8 × VCuS = 250 × 1 × 2  VCuS = 125 ml  eQ.wt of I2 = mol.wtnf = 2542 = 127 

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