Q.

2.56 g of  S8(s) is taken which vapourises and when equilibrium gets established between S8(s) and S(g) then the vapours were found to occupy 960 ml at 1 atm and 273 K. The fraction of S8 (s) undissociated s given by:

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a

0.6

b

0.54

c

0.46

d

0.4

answer is D.

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Detailed Solution

The equilibrium reaction for Sulphur is-

S8(s)      8S(g) 0.01 mole   -

0.01x 8x=96022400x=0.0054

Undissociated= 0.0046

Fraction =0.00460.01=0.46

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