$2.5 g$ of a mixture containing ${\mathrm{CaCO}}_3,\mathrm{Ca}{\left({\mathrm{HCO}}_3\right)}_2$ and $\mathrm{NaCl}$ was dissolved in $100 mL$ water and its $10 mL$portion required $10 mL 0.05 M$ ${\mathrm{H}}_2{\mathrm{SO}}_4$ solution to reach the phenolphthalein end Point Another $10 mL$ portion of the same stock solution required $32.35 mL$ of the same acid solution reach the methyl orange end point. Determine mass percentage ratio of ${\mathrm{CaCO}}_3$ and $\mathrm{Ca}\left({\mathrm{HCO}}_3{)}_2\right.$in the original mixture.