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$2 H_{2} O_{2} \to_{{OH}^{-}}^{I^{-}} 2 H_{2} O + O_{2}$ . Intermediate in this reaction is ……… and order of the reaction is ………….

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${IO}^{-}; 2$

${IO}_{3}^{-}; 2$

${IO}^{-}; 0.5$

${IO}_{2}^{-}; 1$

answer is A.

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Detailed Solution

$H_{2} O_{2} + I^{-} \to_{{OH}^{-}}^{slow} H_{2} O + \underset{Intermediate}{{IO}^{-}} {IO}^{-} + H_{2} O_{2} \overset{fast}{\to} I^{-} + H_{2} O + O_{2} 2 H_{2} O_{2} \to_{{OH}^{-}}^{I^{-}} 2 H_{2} O + O_{2} rate = K [H_{2} O_{2}] [I^{-}]$

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