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Q.

2molal aqueous solution of an electrolyte  X2Y3 is 75% ionized. The boiling point of the solution at 1atm is  [Kb(H2O)=0.52Kkg/mol]

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a

274.76 K

b

377 K

c

376.4 K

d

377.16 K

answer is D.

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Detailed Solution

X2Y32X+3+3Y2
n=5
α=i1n10.75=i151i=4(0.75)+1
=3.0+1
i=4
ΔTb=i×Kb×m
=4×0.52×2
=4.16K
ΔTb=(Tb)soln(Tb)°
(Tb)soln=ΔTb+Tb°
=373+4.16
=377.16K

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