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Q.

2NO2(brown)N2O4(colorless).When the equilibrium mixture is cooled to below O0C, the intensity of brown color decreases. Correct statement about the equilibrium system is

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a

Forward reaction is endothermic

b

Equilibrium constant increases with increase in temperature

c

Equilibrium constant increases with decrease in temperature

d

Backward reaction is endothermic

answer is D.

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Detailed Solution

Since on cooling mixture intensity of brown color decreases indicates that forward reaction is exothermic . For exothermic reactions temperature increases,kc decreases.

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