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Q.

2NOCl(g)2NO(g)+Cl2(g)

In an experiment, 2.0 moles of NOCl was placed in a one – liter flask and the concentration of NO after equilibrium established was found to be 0.4 mol/L. The equilibrium constant at 27oC is _____×104.

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answer is 125.

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Detailed Solution

125×104

                                      2NOCl2NO+Cl2

Initially                            2 mol            0          0
At Equilibrium                 2-0.4          0.4       0.2 = 1.6
KC=[NO]2[Cl2][NOCl]2=(0.4)2(0.2)(1.6)2=0.0125=125×104

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