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3.2 g of S is heated to occupy a volume of 780 ml at $450^{0} C$ and 723 mm pressure. Formula of sulphur is

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$S_{2}$

$S_{4}$

$S_{8}$

answer is D.

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Detailed Solution

$PV = \frac{w}{M} RT$

$\frac{723}{760} \times \frac{780}{1000} = \frac{3 .2}{m} \times 0 .0821 \times 683$

M = 256

$∴ Atomicity = \frac{256}{32} = 8$

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