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Q.

3 moles of an ideal gas (y = 5/3) is subjected to following changes of state.

Identify the correct statement : 

 State A(400 K,2 bar )Reversible  isobaric cooling  State B

TB,PB isothermalexpansion  Reversible  State C

(300 K,1 bar) freeexpansion  Adiabatic  State DTD,0.5 bar 

 

 

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a

TB and TD will be same and equal to 300 K

b

ΔHAD=750 R

c

ΔSAC=0

d

ΔEBD=0

answer is A, D.

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Detailed Solution

PB=2 bar, TB=300 K,TD=300 K

(b) ΔH=nCPΔT=3×58×R×(100)=750R

(c) ΔSAC=3×3R2 in  300400+3×R in 300×2400

(d) TB=TDΔT=0; ΔEBD=0

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