Q.

300 ml of O2 diffused through a porous pot in 50 sec. How long it will take 500 ml of CO2 to diffuse under similar conditions.

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a

97.72 sec

b

5.117 sec

c

26.18 sec

d

9.772 sec

answer is A.

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Detailed Solution

According to Graham's law the rate of diffusion is inversely proportional to square root of its molecular weight

$\frac{r_{\mathrm{O}_{2}}}{r_{\mathrm{CO}_{2}}=\sqrt{\frac{M_{\mathrm{O_{2}}}{M_{\mathrm{C

O}_{2}}}}$

Rate of diffusion of oxygen is

30050=6

Rate of diffusion of carbon dioxide is

500t

4432

6500t=4432

t=50064432

t=5006118

t=97.72 sec

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