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Q.

360 cm3 of CH4 gas diffused through a porous membrane in 15 minutes. Under similar conditions, 120cm3 of another gas diffused in 10 minutes. Find the molar mass of the gas.

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Detailed Solution

Methane
Rate of diffusion of methane
r1= Volume of methane  Time of diffusion of methane 
=360cm315min=24cm3min1
Molar mass of CH4M1=16gmol1
Unknown Gas :
Rate of diffusion of unknown gas
r2= Volume of unknown gas  Time of diffusion 
=120cm310min=12cm3min1
Molar mass of unknown gas (M2) = ?
According to Graham’s law of diffusion
r1r2=M2M1
24cm3min112cm3min1=M216gmol1
Squaring on both sides.
M2=24×24×1612×12=64
Molar mass of the unknown gas = 64g.mol–1

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360 cm3 of CH4 gas diffused through a porous membrane in 15 minutes. Under similar conditions, 120cm3 of another gas diffused in 10 minutes. Find the molar mass of the gas.