Q.

4.5 moles each of hydrogen and iodine heated in a sealed 10 litre vessel. At equilibrium, 3 moles of HI was found. The equilibrium constant for 

H2(g)  +  I2(g)     2HI(g) is

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a

1

b

10

c

5

d

0.33

answer is A.

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Detailed Solution

 

                   H2  +  I2     2HI

Initial conc. 4.5      4.5          0

                     x         x           2x

From question 2x = 3

x=32=1.5

So conc. at equilibrium 4.5 - 1.5 of  H2

= 4.5 - 1.5 of I2 and 3 of HI

K=HI2I2  H2= 3 × 33 ×3=1

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