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Q.

4-amino-3-methylbutanoic acid is treated with thionyl chloride followed by ammonia to obtain compound X. X on reaction with, bromine in an ankaline medium gave compound Y. For estimation, was titrated with perchloric acid. The volume of 0.1 M perchloric acid needed to react with 0.22 g of Y is:

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a

200 mL

b

80 mL

c

120 mL

d

50 mL

answer is A.

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Detailed Solution

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Y + 2HClO4 → Salt

No. of moles of HClO4 needed = 0.22×288=1200 

1200=0.1×VL

VL=120=0.05L=50ml

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