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Q.

4 mole of PCl5 is heated in a 2L vessel to establish an equilibrium [PCl5(g) PCl3(g)+Cl2(g)]. At equilibrium molar concentration of Cl2 is one. The value of Kc for the above equilibrium is

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a

16mole/L

b

13mole/L

c

1 mole/L

d

2M

answer is C.

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Detailed Solution

PCl54(g)PCl30+Cl20
4x2 x2x2
As  x2 = 1  x =2  
    1               1          1
Kc=1×11= 1 mole/L 

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