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Q.

4 mole of pure liquid PA0=80mm of Hg and 6 mole of pure liquid PB0=80mm of Hgare mixed. The vapor pressure of the resulting solution is found to be 90 mm of Hg then

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a

It is an ideal solution

b

The solution shows negative deviation from Raoult's law

c

The solution is formed by the absorption of heat.

d

The solution will boil at higher temperature than expected

answer is B, D.

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Detailed Solution

PT=410×80610×100

= 32 + 60 = 92 mm of Hg

But given pressure = 90 mm of Hg

Which is less than what is predicated by Raoult’s law.

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4 mole of pure liquid PA0=80mm of Hg and 6 mole of pure liquid PB0=80mm of Hgare mixed. The vapor pressure of the resulting solution is found to be 90 mm of Hg then