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Q.

400 ml of 1M NaCl is electrolysed using 0.04F (inert electrodes). After electrolysis pH of the solution left will be

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a

11

b

13

c

12

d

14

answer is A.

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Detailed Solution

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Electrolysis of aq.NaCl gives hydrogen gas at cathode and oxygen gas at anode, the electrolyte solution contains NaOH after electrolysis.
Number of equivalents of NaOH formed =0.04

Normality (N)= 0.04×1000400=0.1N

[OH-]= 0.1N

pOH= -log [OH-]

pOH= -log (0.1) 

pOH =1 

pH+pOH = 14 

pH =14-1 

pH= 13 

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