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Q.

40 ml of a hydrocarbon undergoes combustion in 260ml of oxygen and gives 160ml of CO2. If all volumes are measured under similar conditions, the formula of the Hydrocarbon is 

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a

C4H10

 

b

C4H8 

c

C6H14 

d

C3H8

answer is D.

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Detailed Solution

We know that the combustion reaction is represented as:

CxHy+(x+y/4)O2------> xCO2+y/2H2O

40ml         260ml                                          160ml

For 1ml of CxHy:

40/40             260/40                             160/40

      1                     6.5                                           4

X = 4 as 1 mol of hydrocarbon is producing 4 mol of carbon dioxide. x+y/4=6.5

y = 10

So, formula of hydrocarbon is C4H10 that is butane.

Therefore, Option (D) is correct.

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