Q.

4.14 g of pure lead was dissolved in nitric acid and was made to react with  HCl,  Cl2 and  NH4Cl to convert lead completely into  (NH4)2PbCl6. However, only 2.28 g of (NH4)2PbCl6  was actually produced. The percentage yield of the product is. (Atomic wt. of Pb = 207)

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a

75

b

37.5

c

50

d

25

answer is D.

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Detailed Solution

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 PbHNO3Cl2HClNH4Cl(NH4)2PbCl6
(4.14g)                                                  (2.28g)
Applying POAC on Pb:
1×nPb=1×n(NH4)2PbCl6
1×4.14207=1×m(NH4)2PbCl6(expected)456
m(NH4)2PbCl6(expected)=9.12g
% yield  of  product=2.289.12×100=25%.
 

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