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Q.

4.5 moles each of hydrogen and iodine were heated in a sealed ten litre vessel. At equilibrium 3 moles of HI were found. The equilibrium constant of H2(g)+I2(g)2HI(g) is

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a

0.33

b

10

c

5

d

1

answer is A.

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Detailed Solution

                                H2+I22HI

Initial moles      4.5       4.5       0

Moles at eqm   3          3          3

K=(3)23×3=1 .

Note : when there is no change in the number of moles, Δn=0 the volume or capacity of vessel can be ignored.

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