Q.

4.5 mol each of H2 and I2 are present in a 10 lit vessel. At equilibrium, the mixture contains 3 mole HI, Kp for H2+I22HI and mass of I2 at equilibrium (in g) respectively are

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a

1 ; 0.3

b

1 ; 381

c

1 ; 762

d

4 ; 762

answer is A.

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Detailed Solution

It is given to find the Kpfor H2+I22HI and mass of I2 at equilibrium (in g ) 4.5 mol each of H2 and I2 are present in a 10 lit vessel. At equilibrium the mixture contains 3 mole HI.

4.5 moles each of hydrogen and iodine which is heated in a sealed 1olitre vessel.

H2( g)+I2( g)2HI(g)

I   4.5            4.5             0

C -x               -x               2x

E 4.5-x          4.5- x      2x

2x= 3

x = 1.5

Since 1 mole of H2 and one mole of I2 combine to give 2 moles of HI then 3 moles of HI would be formed by ICE table,

KC=[HI]2H2I2

=[3]2[3][3]

=1

Hence the correct option is (A) 1; 0.3. 

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