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Q.

4g H2 and 127g I2 are mixed & heated in 10 lit closed vessel until equilibrium is reached. If the equilibrium concentration of HI is 0.05 M, total number of moles present at equilbrium is

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a

3.25

b

1.75

c

2.25

d

2.5

answer is D.

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Detailed Solution

{left( {{W_{{H_2}}}} right)_{initial}} = 4g

 

 

{left( {{n_{{H_2}}}} right)_{initial}} = frac{4}{2}=2
{left( {{W_{{I_2}}}} right)_{initial}} = 127g

 

{left( {{n_{{I_2}}}} right)_{initial}} = frac{127}{254}=0.5

 

HIeq=0.05 M, V=10 lit;

therefore 0.05=n_{HI}times;frac{1}{10}

 

 

 

 

nHIeq=0.5 ;

1 mole of Hydrogen gives 2 moles of HI

'X1' moles of Hydrogen gives 0.5 moles of HI.

boxed{{X_1} = 0.25}

Number of moles of Hydrogen reacted (X1) = 0.25

Number of moles of Iodine reacted also will be 0.25

Stoichiometry
mathop {H_2left( g right)}limits^{1,mole}+
mathop {I_2left( g right)}limits^{1,mole}
rightleftharpoons
mathop {2HIleft( g right)}limits^{2,mole}
Initial moles20.5 -
Mole at equilibrium(2 - 0.25)(0.5 - 0.25) 0.5

Total moles at equilibrium = 1.75+0.25+0.5

Total moles at equilibrium = 2.5

 

 

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