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Q.

5.0 cm3 of H2O2 liberates 0.508 g of iodine from an acidified KI solution. The strength of H2O2 solution in terms of volume strength at STP is

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a

7.68 volumes

b

4.48 volumes

c

none of these

d

6.48 volumes

answer is B.

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Detailed Solution

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VH2O2=5 ml WI2 =0.508gr MWI2=2×127=254gr H2O2+2KIH+I2+2KOH 1mole----1 mole           ?? -----   2×10-3 mole 2×10-3×11 M=2×10-3×10005 M=0.4M

For H2O2

10 vol. strength =0.893M = 1.786N = 3.03%(W/V)
?? -------------------------= 0.4M
 0.4×100.893 =40.893=4.47 vol

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