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Q.

5 moles of hydrogen (γ= 7 / 5) intially at S.T.P. are compressed adiabatically so that its temperature becomes 4000C. The increase in the internal energy of the gas in kilo-J is (R=8.30Jmole–1k–1)

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a

21.55

b

41.50

c

65.55

d

80.55

answer is B.

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Detailed Solution

n=5 mole ; γ=75T1=273K;T2=673KdU=?R=8.30J/ mole kCV=1n×(dQ)VdT; here (dQ)V=dUdU=nCVdT=nR/γ1dTdU=5×8.3×4007/51=25×83×402dU=41500J=41.50KJ

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