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Q.

50 gm of 109% oleum is mixed with 50 gm of another 118% oleum. Calculate the maximum weight of H2SO 4H2SO4 which can be obtained from the resulting mixture. (Fill the OMR after multiplying with 10)

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answer is 1135.

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Detailed Solution

Oleum = SO3+H2OH2SO4

100g oleum + 9g H2O

100g oleum SO340y

H2SO410040=60g

moles of  SO3= moles of H2O

x80=918

x=918×80=40y

50 oleum SO34Og 

H2SO410y

Total SO3 = 40+20=60g

Total H2SO4 = 30+10=40y

SO3+H2OH2SO4

moles of SO3 = moles of H2SO4

Wt. of H2SO4 = 50×109+50×118100=113.5%

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