Q.

50 mL of 0.2 molal urea solution (density =1.012gmL1at300k) is mixed with 250 mL of a
solution containing 0.06 g of urea. Both the solutions were prepared in the same solvent. The osmotic pressure (in Torr) of the resulting solution at 300 K is_. 

[Use : Molar mass of urea =60gmol1; gas constant, R=61LTorrK1mol1; Assume, ΔmaxH=0,ΔmixV=0]

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answer is 671.

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Detailed Solution

Weight of 50 ml 0.2 molal urea
Question Image 
Given 0.2 molal implies
1000 gm solvent has 0.2 moles urea
So weight of solution = 1000 + 0.2 × 60 = 1012 gm. 
So wt. of urea in 50.6 gm solution
Question Image
 

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