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Q.

50 mL of 0.1 M NaOH is added to 60 mL of 0.15 M H3PO4 solution K1,K2 and K3 for H3PO4 are 103108 and 1013 respectively). The pH of the mixture would be about (log 2 = 0.3) :

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a

6.5

b

5.5

c

3.1

d

4.1

answer is A.

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Detailed Solution

H3PO4    +    NaOH    NaH2PO4+H2O

60 X 0.15 =9           5                   5 

4                             -                   5

pH=pK1+log54

=3.1

Hence, option A is correct.

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50 mL of 0.1 M NaOH is added to 60 mL of 0.15 M H3PO4 solution K1,K2 and K3 for H3PO4 are 10−3, 10−8 and 10−13 respectively). The pH of the mixture would be about (log 2 = 0.3) :