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Q.

6g of non volatile solute is dissolved in 90g of water, such that the lowering of vapour pressure is 2% . The molecular weight of solute is

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a

60

b

92

c

65

d

80

answer is C.

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Detailed Solution

Wt of non volatile solute W1  = 6g

Wt of solvent (Water)=W2=90g

GMW of solute=M1=?

GMW of solvent H2O=M2=18g

R.L.V.P=pp0=2100  

 According to Raoults law  

 pp0=W1M1×M2W2 

2100=6M1×1890 

 M1=6×182×90×100; M1=60

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6g of non volatile solute is dissolved in 90g of water, such that the lowering of vapour pressure is 2% . The molecular weight of solute is