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Q.

9.2 gm of N2O4(g) is taken in a closed one litre vessel and heated till the following equilibrium is reached N2O4(g)2NO2(g). At equilibrium 50% of N2O4(g) is dissociated. What is the equilibrium constant (in mole lit-1)? (M. wt. of N2O4 is 92)

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a

2

b

0.1

c

0.2

d

0.4

answer is B.

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Detailed Solution

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N2O4 moles =9.292=0.1 moles 

N2O42NO2

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KcNO22N2O4

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9.2 gm of N2O4(g) is taken in a closed one litre vessel and heated till the following equilibrium is reached N2O4(g)⇌2NO2(g). At equilibrium 50% of N2O4(g) is dissociated. What is the equilibrium constant (in mole lit-1)? (M. wt. of N2O4 is 92)