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Q.

93.75% of a 1st order reaction is completed in 120 minutes. If initial concentration of the reactant is 2 mole/lit, the rate of reaction at the end of 120 min is 

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a

2.31×103Mmin1

b

2.88×103Mmin1

c

4.62×102Mmin1

d

6.93×104Mmin1

answer is C.

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Detailed Solution

t93.75%=4×t50%=120min, t50%=1204=30min

K=0.693t12=0.69330=2.31×102min1

Amount left after 120 minits is 0.125 mole/liter.

Rate=K[R]=2.88×103M min1

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