Q.

(A) : Al is more electro positive than Tl. 
(R) : Al2O3 is more basic than Tl2O.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is C.

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Detailed Solution

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Electronegativity order : B > Tl > In > Ga > Al

Electropositivity order : B < Tl < In < Ga < Al

Electropositivity order  ∝ Metallic nature 

Al2O3 is amphoteric oxide.

→ Tl+1 oxidation is more stable. Therefore Tl+1 compounds are more similar to that of  IA group compounds. IA group oxides and hydroxides are basic in nature and hence Tl(OH) and Tl2O are also basic in nature.

Hence basic strength order : Tl2O > Al2O3

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