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Q.

(A) : At constant temperature, PV vs V plot for real gases is not a straight line.
(R) : At high pressure all gases have Z > 1 but at intermediate pressure most gases have Z < 1.

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

c

(A) is true but (R) is false

d

Both (A) and (R) are false

answer is B.

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Detailed Solution

  • PV versus P plot is straight line for ideal gases but not for real gases as inter-molecular forces of attraction are present in real gases whose molecules have finite real sizes and we see deviation from ideal behavior. 
  • At high pressure, there is positive deviation from ideal behaviour (Z > 1) but at intermediate or moderate pressure, the real gases shows negative deviation from ideal behavior (Z < 1).
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