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Q.

(A) : At high pressures repulsive force become significant in gases
(R) : At high pressure gas molecules are almost in contact with each other

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

c

(A) is true but (R) is false

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

  • At high pressures, the repulsive forces between gas molecules become significant because the molecules are more closely packed together. 
  • As the pressure increases, the molecules are forced closer to each other, and their electron clouds begin to overlap, resulting in a repulsive force. 
  • This repulsive force is due to the electrostatic interactions between the molecules and becomes increasingly significant as the distance between the molecules decreases.
  • As the pressure increases, the gas molecules are forced closer together, and at very high pressures, they are almost in contact with each other. 
  • At this point, the intermolecular forces between the molecules become very strong, and the gas can no longer be treated as an ideal gas. 
  • The molecules are so close together that they begin to interact strongly with each other, leading to deviations from ideal gas behavior. 
  • Therefore, statement (R) is also correct.
  • So, both (A) and (R) are correct and (R) is the correct explanation of (A)
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