Q.

(A) : BCl3 has zero dipole moment.
(R) : B–Cl bond has no bond moment.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are true and (R) is not the correct explanation of (A)

answer is C.

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Detailed Solution

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B-Cl bond is polar due to electronegativity difference between B and Cl.
In BCl3​, the central B atom undergoes sp2 hybridization which results in plane triangular geometry. The molecule has symmetry and the individual bond dipoles cancel each other. Hence, the molecule has zero dipole moment.

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