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Q.

(A) : Compressibility factor for hydrogen varies with pressure with positive slope at all pressures
(R) : Even at low pressures, repulsive forces dominate in hydrogen gas

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

c

(A) is True but (R) is False

d

Both (A) and (R) are false

answer is A.

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Detailed Solution

  • In case of hydrogen, compressibility factor (Z) increases with pressure. 
  • At 273K, Z > 1, which show that it is difficult to compress the gas. In this case repulsive forces dominate. Note: For ideal gases, Z = 1. For real gases, Z 1.
  • If Z < 1, negative deviation and the gas is more compressible than expected.
  • If Z > 1, positive deviation and the gas is less compressible than expected.

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