Q.

(A) : Critical temperature is the temperature at which the real gas exhibits ideal behaviour for considerable range of pressure.
(R) : At critical point the densities of a substance in gaseous and liquid states are different

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A)

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

c

(A) is True but (R) is False

d

Both (A) and (R) are false

answer is C.

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Detailed Solution

  • Temperature at which the real gas exhibits ideal behaviour for considerable range of pressure is known as Boyle's temperature Tb=a/bR, where a and b are van der Waals' constants. 
  • Critical temperature is the temperalure above which, the gas cannot be liquefied, how so ever high pressure may be applied : Tc = 8a/27Rb.
  • At the critical point, the densities of substance in gaseous and liquid state are same.
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