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Q.

(A) : Electron affinity of oxygen is less than nitrogen but larger than fluorine.
(R) : Atomic size increases and non metallic character decreases in a period from left to right.

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a

(A) is true but (R) is false

b

Both (A) and (R) are true but (R) is not the correct explanation of (A)

c

Both (A) and (R) are true and (R) is the correct explanation of (A)

d

Both (A) and (R) are false

answer is D.

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Detailed Solution

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Electron affinity of N is essentially zero because of its exactly half-filled electronic configuration.
Further because F has 7 electrons and O has 6 electrons in the valence shell, therefore the tendency of F to acquire additional electron is higher than that of O, i.e., EA of F is higher than that O. In other words, EA decreases as F > O > N.

In a period from left to right, non metallic character increases as atomic size decreases.

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