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Q.

A : Entropy of a perfect crystalline substance at absolute zero is zero. 

R : At absolute zero, the translational kinetic energy of a system is zero.

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a

Both A and R are true, and R is the correct explanation 

b

Both A and R are true but R is not the correct explanation of A 

c

A is true but R is false 

d

A is false but R is true

answer is A.

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Detailed Solution

  • Enthalpy and entropy of any elementary substance in their standard states are taken as zero because, at absolute zero, particles of the perfectly crystalline substance become completely ordered.
  • The entropy of a perfect crystalline substance at absolute zero is zero. At absolute zero, the translational kinetic energy of a system is zero.

So, Both A and R are true, and R is the correct explanation.

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