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Q.

(A) : Gases do not liquefy above their critical temperature, even on applying high pressure
(R) : Above critical temperature, the molecular speed is high and intermolecular attractions cannot hold the molecules together because they escape due to high speed.

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a

(A) is true but (R) is false

b

Both (A) and (R) are correct and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

Both (A) and (R) are correct but (R) is not the correct explanation of (A)

answer is A.

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Detailed Solution

  • The critical temperature of a gas is the temperature above which it cannot be liquefied, regardless of the pressure applied to it. 
  • This is because, at the critical temperature, the gas is in a state where its density is too low and its kinetic energy is too high for the intermolecular forces to hold the gas molecules together.
  • At temperatures above the critical temperature, the kinetic energy of the gas molecules is so high that the intermolecular forces of attraction are not strong enough to keep the molecules together. 
  • The molecules move too quickly and tend to escape from each other due to their high speed.
  • This means that no matter how much pressure is applied to the gas, the intermolecular forces are not strong enough to cause the gas to liquefy. 
  • Therefore, statement (R) correctly explains why gases do not liquefy above their critical temperature.
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