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Q.

(A) : Half-life period of a reaction of first order is independent of initial concentration.
(R) : Half-life period for a first order reaction is equal to 2.303 Klog2

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a

Both (A) and (R) are correct and (R) is the correct explanation of (A).

 

b

Both (A) and (R) are correct but (R) is not the correct explanation of (A).

 

c

(A) is correct but (R) is wrong.

 

d

(A) and (R) both are wrong.

answer is A.

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Detailed Solution

For a first order reaction,K=2.303tlogaa-x, where a is initial concentration, and x is the amount reacted in time t.
For half-life x=a/2·t=t1/2
K=2.303 Klogaa-a/2
t1/2=2.303 Klog2=0.693 K

 

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