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Q.

(A) : If the activation energy of a reaction is zero, temperature has no effect on the rate constant.
(R) : Lower the activation energy, faster is the reaction.

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a

Both (A) and (R) are correct but (R) is not the correct explanation of (A).

 

b

(A) is correct but (R) is wrong.

 

c

Both (A) and (R) are correct and (R) is the correct explanation of (A).

 

d

(A) and (R) both are wrong.

answer is B.

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Detailed Solution

The Arrhenius expression is k=Ae-EaRT.
When the activation energy is zero, the term e-EaRT becomes equal to 1 . Hence, the rate constant becomes independent of the temperature.
When the value of the activation energy is low, the value of the rate constant is higher. Hence, the rate of the reaction is also high.

Therefore, the correct option is (B).

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